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1.
NING Chuanxiang MA Zhongliang JIANG Zhenxue SU Siyuan LI Tingwei ZHENG Lunju WANG Guozhen LI Fengxun 《《地质学报》英文版》2020,94(2):352-363
To reveal the effect of shale reservoir characteristics on the movability of shale oil and its action mechanism in the lower third member of the Shahejie Formation(Es3l), samples with different features were selected and analyzed using N2 adsorption, high-pressure mercury injection capillary pressure(MICP), nuclear magnetic resonance(NMR), high-speed centrifugation, and displacement image techniques. The results show that shale pore structure characteristics control shale oil movability directly. Movable oil saturation has a positive relationship with pore volume for radius > 2 μm, as larger pores often have higher movable oil saturation, indicating that movable oil is present in relatively larger pores. The main reasons for this are as follows. The relatively smaller pores often have oil-wetting properties because of organic matter, which has an unfavorable effect on the flow of oil, while the relatively larger pores are often wetted by water, which is helpful to shale oil movability. The rich surface provided by the relatively smaller pores is beneficial to the adsorption of immovable oil. Meanwhile, the relatively larger pores create significant pore volume for movable oil. Moreover, the larger pores often have good pore connectivity. Pores and fractures are interconnected to form a complex fracture network, which provides a good permeability channel for shale oil flow. The smaller pores are mostly distributed separately;thus, they are not conducive to the flow of shale oil. The mineral composition and fabric macroscopically affect the movability of shale oil. Calcite plays an active role in shale oil movability by increasing the brittleness of shale and is more likely to form micro-cracks under the same stress background. Clay does not utilize shale oil flow because of its large specific surface area and its block effect. The bedding structure increases the large-scale storage space and improves the connectivity of pores at different scales, which is conducive to the movability of shale oil. 相似文献
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黔北镇远牛蹄塘组黑色页岩沉积环境与有机质富集关系 总被引:1,自引:0,他引:1
通过矿物组分、主量元素、微量元素、碳氧同位素等特征,分析了黔北地区镇远县ZX井牛蹄塘组黑色页岩的岩相类型和不同岩相页岩的沉积环境及其与有机质富集间的关系。结果表明,牛蹄塘组下段以硅质页岩为主,TOC含量4. 96%~10. 10%;上段以富泥硅质页岩为主,TOC含量1. 43%~9. 04%。下段硅质页岩沉积于水流停滞的深水陆棚环境,沉积古水体为贫氧的还原状态;上段富泥硅质页岩沉积时期,仍为贫氧的还原环境,但水体滞留程度、还原性较下段硅质页岩沉积期弱。贫氧的还原环境是影响牛蹄塘组黑色页岩有机质富集的主要因素,热液作用和陆源碎屑对牛蹄塘组黑色页岩有机质富集的影响较小。 相似文献
3.
YANG Kai ZHANG Bing WANG Xuben HE Lanfang YANG Hongyu WANG Pengwan TANG Jialin DENG Jixin ZHANG Cong 《《地质学报》英文版》2020,94(5):1531-1546
The Lower Silurian Longmaxi Formation in the south of Sichuan is a key player in the exploration and development of shale gas in China. Due to a highly complex topographic area, electromagnetic methods (EM) become important exploration means in this area. Many studies have been conducted on the shale mineral composition and electrical properties of shale, however, the correlation between sedimentary environments and the electrical properties of shale remain poorly understood. The electrical properties and sedimentary environment of the organic-rich shale of the Longmaxi Formation have been studied by means of X-ray diffraction, organic geochemistry, scanning electron microscopy and complex resistivity measurements. The discovered high quartz content of the Longmaxi Formation shale results in low resistivity. Deep-water shelf biogenic quartz contributes lower resistivity more than that of shallow-water terrigenous quartz. The deep-water anoxic and organic sedimentary environment led to major enrichment of pyrite, leading to a high polarization effect in shale. We present the correlation between the lithofacies types and electrical properties of Longmaxi Formation. The mixed siliceous shale lithofacies is the most favorable among the three lithofacies, which is characterized by high total organic carbon (TOC) content, high brittleness mineral content, high polarization and low resistivity (“three high and one low”). This feature is an effective identification of shale gas reservoirs by electromagnetic prospecting. Our study can provide constraints on electrical parameters of rocks for electromagnetic “sweet spot” exploration of shale gas, and so this has important geological significance to shale gas exploration and development. 相似文献
4.
海陆过渡相富有机质泥页岩是页岩气勘查开发的重要领域。本文以西昌盆地上三叠统白果湾组富有机质泥页岩为研究对象,对研究区内富有机质泥页岩的沉积岩相古地理特征、微观孔隙类型、孔隙结构特征进行研究。白果湾组富有机质泥页岩段沉积相主要为湖泊相、三角洲相、河流相。发育不同类型的微孔隙,孔隙主要以小孔为主,微孔次之,平均孔径分布在5.56~56.89nm之间,比表面积平均为9.44m2/g,总孔体积平均为0.0187cm3/g。页岩气主要形成于滨浅湖亚相及半深湖亚相中,并主要吸附于富有机质泥页岩的小孔、微孔内;西昌盆地白果湾组富有机质泥页岩储集空间较好,具有良好的勘探潜力。 相似文献
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为查明沾化凹陷罗家地区古近系沙河街组三段下亚段页岩油的储层特征及其影响要素,通过岩心、薄片、扫描电镜等多种资料综合分析,开展页岩油储层岩性、储层空间类型、影响因素及页岩油储层评价参数的研究。结果表明: 综合矿物成分和沉积构造2个因素,可将研究区页岩油储层岩性划分为7种类型; 不同岩性储集空间发育有较大差异,纹层状泥质灰岩和纹层状灰岩储集空间最为发育,纹层状灰质泥岩储集空间较发育,块状泥岩储集空间发育一般,块状泥质灰岩、块状灰质泥岩及纹层状粉砂岩储集空间发育较差; 研究区页岩油储层储集空间的发育主要受矿物成分、沉积构造、有机质含量和赋存方式以及成岩作用的影响。以此为基础,选取方解石含量、纹层状构造、总有机碳(Total Organic Carbon,TOC)含量、镜质体反射率(Ro)及孔隙度作为页岩油储层评价参数,将沾化凹陷罗家地区页岩油储层分为优质储层、有利储层和不利储层3类。 相似文献
7.
作为重要的土壤物理性质,膨胀性在影响土壤导水性、持水性、抗蚀性以及土壤结构的形成和发育等方面发挥着重要作用。为了探讨生物土壤结皮(BSCs)土壤的膨胀特性及其主要影响因素,针对黄土高原风沙土和黄绵土两种典型土壤,利用膨胀仪测定并比较了有、无藓结皮及其在不同因素(初始含水量、干湿循环、冻融循环、温度)下膨胀率的差异,分析了BSCs对土壤膨胀性的影响及其与环境因素和BSCs性质的关系。结果显示:风沙土上藓结皮的膨胀率为1.93%,较无结皮增加了8.65倍;而黄绵土上藓结皮的膨胀率为2.05%,与无结皮相比降低了76.68%。藓结皮的生物量和厚度与其膨胀率在风沙土上均呈线性正相关关系(P < 0.05),在黄绵土上分别呈二次函数(P=0.02)和线性正相关关系(P=0.02)。初始含水量同时影响了土壤最大膨胀率和稳定膨胀时间,影响程度风沙土远大于黄绵土(包括藓结皮和无结皮);干湿循环次数对无结皮土壤膨胀率的影响程度大于藓结皮土壤,其中风沙土和黄绵土上无结皮的膨胀率分别是50.00%~620.00%和-2.28%~10.81%,而两种土壤上藓结皮的膨胀率分别是-5.70%~10.88%和-10.24%~-21.46%;冻融循环下4种土壤的膨胀率均有不同程度的降低,降幅为0~18.54%。黄绵土无结皮的膨胀率受温度影响程度较大,50℃下黄绵土无结皮的膨胀率分别是25℃和35℃下的1.17倍和1.21倍。BSCs显著地改变了风沙土和黄绵土表层的膨胀性,其影响的程度和方向取决于土壤类型。同时,BSCs的膨胀性受含水量、温度、干湿以及冻融循环等关键因素影响。 相似文献
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